Last edited by Sacage
Wednesday, July 29, 2020 | History

2 edition of N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis found in the catalog.

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis

by Catherine Suzanne Julienne Cazin

  • 6 Want to read
  • 33 Currently reading

Published by Springer Science+Business Media B.V. in Dordrecht .
Written in English

    Subjects:
  • Organic Chemistry,
  • Catalysis,
  • Chemistry

  • Edition Notes

    Statementedited by Catherine S.J. Cazin
    SeriesCatalysis by Metal Complexes -- 32
    ContributionsSpringerLink (Online service)
    The Physical Object
    Format[electronic resource] /
    ID Numbers
    Open LibraryOL25538146M
    ISBN 109789048128655, 9789048128662

      N-Heterocyclic carbenes (NHCs), which were first isolated in the early s, have received a great deal of scientific attention as ligands for transition metal complexes and organocatalysts for Cited by: This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures. Written by leading international experts this is a valuable and practical source for every organic chemist.

    ISBN: X OCLC Number: Description: xvi, pages: illustrations ; 25 cm. Contents: 1. N-heterocyclic carbenes: an introductory overview N-heterocyclic carbene complexes N-heterocyclic carbene complexes in olefin metathesis N-heterocyclic carbene complexes in polymerisation, oligomerisation and . During the last decade, there has been a great progress in the field of N-heterocyclic carbenes and their use in organocatalysis. The book is giving an excellent overview about the synthesis and applications of NHCs focussing on carbon-carbon and carbon-heteroatom bond formation.

    N-Heterocyclic Carbene Complexes in Industrial Processes.\/span>\"@ en\/a> ; \u00A0\u00A0\u00A0\n schema:description\/a> \" \"N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis\" features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition. The use of NHCs in asymmetric transition-metal catalysis is highlighted, as are recyclable systems (biphasic, covalently immobilized, and ionically tagged systems), NHCs in flow chemistry, and recent advances in the use of NHCs in organocatalysis. Volume Editor's Preface. N-Heterocyclic Carbenes in Catalytic Organic Synthesis Volume 1 (TOC.


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N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis by Catherine Suzanne Julienne Cazin Download PDF EPUB FB2

About this book Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts.

An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. "This book is a review of N-heterocyclic carbene ligands (NHCs), their preparation, and use in transition metal catalysis. It is divided into seven chapters, each of which is written by an expert on that particular topic, which is reflected in the thoroughness of coverage.

Over the last fifteen years, N-heterocyclic carbenes (NHCs) have mostly been used as ancillary ligands for the preparation of transition metal-based catalysts.

Compared to phosphorus-containing ligands, NHCs tend to bind more strongly to metal centres, avoiding the necessity for the use of excess ligand in catalytic reactions.

The corresponding complexes are often less sensitive to air and. It was only in the early s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated.

Since the first report on the application of NHCs as ligands in transition metal catalysis. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis: Authors: Cazin, Catherine S. Publication: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis: Catalysis by Metal Complexes, Volume ISBN Springer Science+Business Media B.V., Publication Date: 00/ Origin.

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis, by Cazin, Catherine S.J., ISBN Springer Science+Business Media B.V.,p.

Publication Date. About this book. This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in.

[1(a)], [3] Notably, N-heterocyclic carbenes (NHCs), as well as other stable carbene systems, are broadly utilized as ligands in transition-metal chemistry, but their carbene-metal bonds are Author: Frank Glorius.

N-heterocyclic carbenes are cyclic molecules that contain one carbene and at least one nitrogen atom within the carbene-containing ring structure. These molecules are widely used as ancillary ligands for the preparation of transition-metal-based catalysts and can be highly active organocatalysts in their own by: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts.

An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly : Hardcover. N-Heterocyclic Carbenes In Transition Metal Catalysis Frank Glorius It was only in the early s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated.

N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. “Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis” presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis.

Cazin, Catherine, editor. N-Heterocyclic Carbenes in Transition Metal Catalysis and 32, Springer, Cited by: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs.

This group of contributors is complemented by highly established academic researchers and an Brand: Catherine S J Cazin. About this book In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts.

This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Description: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts.

An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos.

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or. From the Inside Flap. In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts.

This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of.

Description. Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation.

Alongside comprehensive coverage of the. Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications.

Chemical Reviews(18), DOI: / by: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as.Catalysts, an international, peer-reviewed Open Access journal.

Dear Colleagues, Over the last 30 years, N-Heterocyclic carbenes (NHCs) have had a profound impact on catalysis and on organometallic chemistry in widely tuneable electronic and steric features have contributed significantly to their recognition as both: 1) an important class of ligands in organometallic chemistry.